Expedient synthesis of 8-aza-1-hydroxy-2,3-dioxabicyclo[4.3.0]nonan-7-ones using manganese(III)-catalyzed aerobic oxidation

Heterocyclic communications

article

Md. Aminul Haque¹  Hiroshi Nishino¹ 

[1] Department of Chemistry, Graduate School of Science and Technology, Kumamoto University

关键词: catalytic oxidation;    endoperoxidation;    endoperoxides;    manganese(III) acetate;    2;    4-pyrrolidinediones;   

DOI  :  10.1515/HC.2010.005

学科分类：内科医学

来源: De Gruyter

【 摘 要 】

The reaction of 3-alkyl-2,4-pyrrolidinediones with 1,1-diarylethenes in the presence of a catalytic amount of manganese(III) acetate resulted in the aerobic endoperoxidation that produced very stable crystalline 8-aza-1-hydroxy-2,3-dioxabicyclo[4.3.0] nonan-7-ones in high yields.

【 授权许可】

CC BY|CC BY-NC-ND