Tertiary formylated amines by microwave irradiation of N,N-dimethyl-N′-(2-pyridyl)formamidines with methyl vinyl ketone

Heterocyclic communications

article

Omar Gómez-García¹  Héctor Salgado-Zamora¹  Elena Campos-Aldrete¹ 

[1] Departamento Química Orgánica, Escuela Nacional de Ciencias Biológicas-IPN

关键词: amidines;    methyl vinyl ketone;    microwave irradiation;   

DOI  :  10.1515/hc-2013-0196

学科分类：内科医学

来源: De Gruyter

【 摘 要 】

Treatment of N , N -dimethyl- N ′-(2-pyridyl)formamidine with methyl vinyl ketone under microwave irradiation yields N -formyl- N -(3-oxobutyl)-2-pyridylamine without decomposition or polymerization of methyl vinyl ketone. The result is an alternative non-oxidative approach to the preparation of N -formyl-substituted aminoketones.

【 授权许可】

CC BY|CC BY-NC-ND