Metallocyclodextrins: Combining Cavitands with Metal Centres

ChemistryOpen

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关键词: cavitands;    CC bond formation;    cyclodextrins;    oschelation;    phosphanes;   

DOI  :  10.1002/open.201300033

来源: Wiley

【 摘 要 】

Abstract

Non-conventional coordination chemistry occurs upon encapsulation of metal fragments in the cavity of a β-cyclodextrin-derived diphosphane (WIDEPHOS). It was found possible to form otherwise unstable metal species and slow down coordination processes, allowing the elucidation of novel mechanistic pathways for carboncarbon bond-forming reactions.

【 授权许可】

Unknown   
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