O desafio da ativação das ligações C-H em síntese orgânica

Química Nova

Francisco De Azambuja¹  Carlos Roque Duarte Correia¹ 

[1] ,Universidade Estadual de Campinas Instituto de Química Campinas SP ,Brasil

关键词: C-H activation;    transition metals;    organic synthesis;   

DOI  :  10.1590/S0100-40422011001000011

来源: SciELO

【 摘 要 】

This review aims at to the presentation and discussion of the principal aspects of the C-H activation by transition metals. Representative examples were selected from the recent literature to illustrate these principles beginning with somewhat simple examples and moving up to more complex ones. The synthetic potential of the C-H activation, as well as the potential advantages and disadvantages of the methodology are highlighted with relevant recent examples, along with brief insights on the mechanism aspects of these reactions.

【 授权许可】

CC BY-NC   
 All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License