Síntese de complexo ferro(II)-nitrogênio: abordagem dos conceitos de reatividade e retro-doação para alunos de graduação em química

Química Nova

Fábio L. Pissetti¹  Rogério S. Nonô¹  Yoshitaka Gushikem¹  Gilson H. M. Dias¹ 

[1] ,Universidade Estadual de Campinas Instituto de Química Campinas SP ,Brasil

关键词: iron;    edta;    dinitrogen;   

DOI  :  10.1590/S0100-40422007000300037

来源: SciELO

【 摘 要 】

There has been a considerable interest in coordination complexes of molecular nitrogen (N2), partly due to a possible relationship between such complexes and the nitrogen activation process in nature. The present paper describes the synthesis and infrared spectroscopic characterization of an iron-nitrogen derivative with ethylenediamine-N,N,N',N'-tetraacetate (edta) as an experiment for an undergraduate course. The topics covered here include synthesis, reactivity and spectroscopy.

【 授权许可】

CC BY-NC   
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