Synthesis of the iron(II)-nitrogen complex: concepts of reactivity and back-bonding for undergraduate chemistry students

Química Nova

Gushikem, Yoshitaka¹  Nonô, Rogério S.¹  Pissetti, Fábio L.¹  Dias, Gilson H. M.¹  Universidade Estadual de Campinas, Campinas, Brasil¹ 

关键词: iron;    edta;    dinitrogen.;   

DOI  :  10.1590/S0100-40422007000300037

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

There has been a considerable interest in coordination complexes of molecular nitrogen (N2), partly due to a possible relationship between such complexes and the nitrogen activation process in nature. The present paper describes the synthesis and infrared spectroscopic characterization of an iron-nitrogen derivative with ethylenediamine-N,N,N',N'-tetraacetate (edta) as an experiment for an undergraduate course. The topics covered here include synthesis, reactivity and spectroscopy.

【 授权许可】

Unknown