Zinc, Lithium and Magnesium Carbenoids: Chemical Properties and Relevant Applications in Organic Synthesis

Journal of the Brazilian Chemical Society

Rodolfo H. V. Nishimura¹  Valter E. Murie¹  Rafael A. Soldi¹  João L. C. Lopes¹  Giuliano C. Clososki¹ 

关键词: carbenoid;    organometallic;    reactive intermediate;    stereospecific synthesis;   

DOI  :  10.5935/0103-5053.20150218

来源: SciELO

【 摘 要 】

Carbenoids are a class of highly reactive reagents that play an important role in modern organic synthesis. These species are very similar to singlet state carbenes since they have an ambiphilic character and react by a concerted mechanism allowing stereospecific transformations. Herein, we discuss these and other chemical aspects of zinc, lithium and magnesium carbenoids as well as relevant applications of these intermediates in organic synthesis.

【 授权许可】

CC BY   
 All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License