Synthesis of Dithiocarbamates by Markovnikov Addition Reaction in PEG and Their Application in Amidoalkylation of Naphthols and Indoles

Journal of the Brazilian Chemical Society

Azim Ziyaei Halimehjani¹  Arefeh Dadras¹  Meraj Ramezani¹  Elham V. Shamiri¹  Seyyed E. Hooshmand¹  Mohammad M. Hashemi¹ 

关键词: dithiocarbamate;    Markovnikov addition;    alkyl vinyl ether;    N-vinylpyrrolidone;    polyethylene glycol;   

DOI  :  10.5935/0103-5053.20150119

来源: SciELO

【 摘 要 】

Synthesis of dithiocarbamates by the one-pot three-component Markovnikov addition reaction of an amine, carbon disulfide and an alkyl vinyl ether or N-vinylpyrrolidone is reported in polyethylene glycol (PEG) under a mild and green procedure with high yields and completely regiospecific. Also, the products were used as efficient starting materials for amidoalkylation of electron-rich arenes such as naphthols and indoles.

【 授权许可】

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