Synthesis of Dithiocarbamates by Markovnikov Addition Reaction in PEG and Their Application in Amidoalkylation of Naphthols and Indoles

Journal of the Brazilian Chemical Society

Kharazmi University, Tehran, IR¹  Shamiri, Elham V.¹  Halimehjani, Azim Ziyaei¹  Hooshmand, Seyyed E.¹  Hashemi, Mohammad M.¹  Ramezani, Meraj¹  Sharif University of Technology, Tehran, IR¹  Dadras, Arefeh¹ 

关键词:  dithiocarbamate;    Markovnikov addition;    alkyl vinyl ether;    N-vinylpyrrolidone;    polyethylene glycol;   

DOI  :  10.5935/0103-5053.20150119

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

Synthesis of dithiocarbamates by the one-pot three-component Markovnikov addition reaction of an amine, carbon disulfide and an alkyl vinyl ether or N-vinylpyrrolidone is reported in polyethylene glycol (PEG) under a mild and green procedure with high yields and completely regiospecific. Also, the products were used as efficient starting materials for amidoalkylation of electron-rich arenes such as naphthols and indoles.

【 授权许可】

Unknown