Journal of the Brazilian Chemical Society | |
Preparation and electrochemical properties of homogeneous carbon-coated LiFe0.9Mn0.1PO4 as cathode material for lithium-ion batteries | |
Yang Xu1  Jingang Yu1  Sui Peng1  Suqin Liu1  Zhongqiang Wei1  Xianhong Li1  Yajuan Li1  | |
[1] ,Central South University College of Chemistry and Chemical Engineering Changsha Hunan ,China | |
关键词: Mn-doping; LiFePO4; cathode material; lithium-ion batteries; | |
DOI : 10.1590/S0103-50532012000700014 | |
来源: SciELO | |
【 摘 要 】
Homogeneous carbon-coated LiFe0.9Mn0.1PO4 cathode material was synthesized by one-step solid-state reaction using glucose as carbon source. Powder X-ray diffractometry (XRD), transmission electron microscopy (TEM), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic measurements were employed to characterize the samples. Mn-doping and carbon co-modification did not affect the olivine structure of LiFePO4, but improved its kinetics in terms of capacity delivery, polarization and rate capability. When compared with the undoped LiFePO4/C, the LiFe0.9Mn0.1PO4/C sample presented good size distribution - around 100-200 nm - and better electrochemical performance. At current rates of 0.1, 1.0, 3.0 and 10.0 C (C = 170 mA g-1), the LiFe0.9Mn0.1PO4/C electrode delivered discharge capacities of 154.1, 138.8, 120.0 and 94.0 mA h g-1, respectively. Results obtained by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) indicated that the polarization and charge transfer resistance of the sample were greatly decreased by Mn-doping.
【 授权许可】
CC BY
All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License
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