Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl

Journal of the Brazilian Chemical Society

Brahim Boualy¹  Larbi El Firdoussi¹  Mustapha Ait Ali¹  Abdellah Karim¹ 

[1] ,Université Cadi Ayyad Faculté des Sciences Semlalia Département de ChimieMarrakech,Morocco

关键词: monoterpenes;    allylic chlorination;    molybdenum;    sodium hypochlorite;   

DOI  :  10.1590/S0103-50532011000700010

来源: SciELO

【 摘 要 】

MoCl5 is applied as efficient agent in allylic chlorination of terpenic olefins in the presence of NaOCl as chlorine donor. Various terpenes are converted to the corresponding allylic chlorides in moderate to good yield under mild and optimized reaction conditions. Different molybdenum precursors are also studied. Among them, MoO3 gives good yield, but after a longer reaction time.

【 授权许可】

CC BY   
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