期刊论文详细信息
| Journal of the Brazilian Chemical Society | |
| Allylic chlorination of terpenic olefins using a combination of MoCl5 and NaOCl | |
| Université Cadi Ayyad, Marrakech, Morocco1 Firdoussi, Larbi El1 Karim, Abdellah1 Ali, Mustapha Ait1 Boualy, Brahim1 | |
| 关键词: monoterpenes; allylic chlorination; molybdenum; sodium hypochlorite; | |
| DOI : 10.1590/S0103-50532011000700010 | |
| 学科分类：化学（综合） | |
| 来源: SciELO | |
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【 摘 要 】
MoCl5 is applied as efficient agent in allylic chlorination of terpenic olefins in the presence of NaOCl as chlorine donor. Various terpenes are converted to the corresponding allylic chlorides in moderate to good yield under mild and optimized reaction conditions. Different molybdenum precursors are also studied. Among them, MoO3 gives good yield, but after a longer reaction time.
【 授权许可】
Unknown
【 预 览 】
| Files | Size | Format | View |
|---|---|---|---|
| RO201912050581372ZK.pdf | 1335KB |  download |
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