Epoxidação do óleo de soja com o sistema catalítico [MoO2(acac)2]/TBHP EM [bmim][PF6]

Química Nova

Maritana Farias²  Márcia Martinelli¹ 

[1] ,IInstituto Federal de Educação, Ciência e Tecnologia Sul-rio-grandensePelotas RS ,Brasil

关键词: soybean oil;    epoxidation;    ionic liquids;   

DOI  :  10.1590/S0100-40422012000800009

来源: SciELO

【 摘 要 】

Epoxidation of soybean oil was investigated using 1-n-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6] ionic liquid as biphasic medium with molybdenum(VI) acetylacetonate complex and tert-butyl hydroperoxide TBHP as oxidizing agent. Reaction conditions were molar ratio TBHP:number of double bonds of oil:catalyst of 100:100:1, reaction temperature of 60 ºC and reaction time between 2 and 24 h. The proposed system showed catalytic activity for epoxidation reactions under tested conditions. Reuse of ionic liquid/catalyst system for epoxidation reactions was also investigated. Evaluation of epoxidation observed in this catalytic system was done by quantitative ¹H NMR data.

【 授权许可】

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