Epoxidation of soybean oil with [MoO2(acac)2]/TBHP CAtalytic system in [bmim][PF6]

Química Nova

IInstituto Federal de Educação, Ciência e Tecnologia Sul-rio-grandense, Pelotas, Brasil¹  Martinelli, Márcia¹  Universidade Federal do Rio Grande do Sul, Porto Alegre, Brasil¹  Farias, Maritana¹ 

关键词: soybean oil;    epoxidation;    ionic liquids.;   

DOI  :  10.1590/S0100-40422012000800009

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

Epoxidation of soybean oil was investigated using 1-n-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6] ionic liquid as biphasic medium with molybdenum(VI) acetylacetonate complex and tert-butyl hydroperoxide TBHP as oxidizing agent. Reaction conditions were molar ratio TBHP:number of double bonds of oil:catalyst of 100:100:1, reaction temperature of 60 ºC and reaction time between 2 and 24 h. The proposed system showed catalytic activity for epoxidation reactions under tested conditions. Reuse of ionic liquid/catalyst system for epoxidation reactions was also investigated. Evaluation of epoxidation observed in this catalytic system was done by quantitative 1H NMR data.

【 授权许可】

Unknown