Catalisadores contendo carbenos n-heterocíclicos como ligantes: propriedades, sínteses, aplicações e comparação com outros ligantes

Química Nova

Julio Cezar Pastre¹  Carlos Roque Duarte Correia¹ 

[1] ,Universidade Estadual de Campinas Instituto de Química Campinas SP ,Brasil

关键词: N-heterocyclic carbenes;    catalysts;    ligands;   

DOI  :  10.1590/S0100-40422008000400028

来源: SciELO

【 摘 要 】

N-heterocyclic carbenes (NHCs) have become of considerable importance in modern organometallic chemistry and homogeneous catalysis. There are several advantages in the use NHCs over their phosphorus analogues, which explains the enormous development of NHC ligands in the field of organometallic catalysis in the past few years. In this article, we present an overview of the importance of the catalysts containing NHC ligands, their synthesis, some pertinent synthetic applications, and a brief comparison with other catalysts.

【 授权许可】

CC BY-NC   
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