期刊论文详细信息
Molecules | |
A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent | |
Piotr Luliński1  Maciej Sosnowski1  | |
[1] Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, Banacha 1, PL 02-097 Warsaw, Poland | |
关键词: Arenes; iodoarenes; aromatic iodination; sodium periodate; periodyl organic intermediates.; | |
DOI : 10.3390/10030516 | |
来源: mdpi | |
【 摘 要 】
Benzene, halobenzenes and some deactivated arenes readily reacted inanhydrous NaIO4/AcOH/Ac2O/concd. H2SO4 mixtures to afford, after quenching withexcess aqueous Na2SO3 solution (a reducing agent), purified iodinated products in 27-88% yields. This novel method of aromatic iodination is simple, fairly effective andenvironmentally safe.
【 授权许可】
CC BY
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
【 预 览 】
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RO202003190060040ZK.pdf | 78KB | download |