Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

Molecules

Hideyo Takahashi¹ 

[1] id="af1-molecules-10-00901">Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Kanagawa 199-0195, Japan. Tel. [phone], Fax. [phone]

关键词: Glycosidase inhibitor;    Ferrier-II reaction;    palladium chloride;   

DOI  :  10.3390/10080901

来源: mdpi

【 摘 要 】

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl₂.

【 授权许可】

Unknown   
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