期刊论文详细信息
Molecules | |
Synthesis of α,β-Unsaturated Ketones as Chalcone Analogues |
|
Christophe Curti1  Armand Gellis1  | |
[1] id="af1-molecules-12-00797">Laboratoire de Chimie Organique Pharmaceutique, UMR CNRS 6517, Université de la Méditerranée, Faculté de Pharmacie, 27, boulevard Jean Moulin, 13385 Marseille Cedex 05, Fran | |
关键词: SRN1; nitrothiophene; nitrophenylethanone; α; β-unsaturated ketones; chalcones; | |
DOI : 10.3390/12040797 | |
来源: mdpi | |
【 摘 要 】
An electron-transfer chain reaction between 2-nitropropane anion and α-bromoketones derived from nitrobenzene and nitrothiophene was demonstrated by mechanistic study and a specific convenient synthetic protocol. Thus, 2-bromo-1-(5-nitrothiophen-2-yl)ethanone or 2-bromo-1-(4-nitrophenyl)ethanone were reacted with several cyclic nitronate anions to form α,β-unsaturated ketones
【 授权许可】
Unknown
© 2007 by MDPI (http://www.mdpi.org).
【 预 览 】
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