International Journal of Molecular Sciences | |
Oxidation of Isoeugenol by Salen Complexes with Bulky Substituents | |
Anika Salanti1  Marco Orlandi2  Eeva-Liisa Tolppa2  | |
[1] Dipartimento di Scienze dell’Ambiente e del Territorio, Università degli Studi di Milano-Bicocca, Piazza della Scienza, 1, 20126, Milano, Italy; | |
关键词: salen; isoeugenol; dehydrogenative polymerization; GPC; NMR; | |
DOI : 10.3390/ijms11030912 | |
来源: mdpi | |
【 摘 要 】
The catalytic properties of bulky water-soluble salen complexes in the oxidation of isoeugenol (2-methoxy-4-(1-propenyl) phenol) have been investigated in aqueous ethanol solutions in order to obtain a mixture of polymeric compounds through dehydrogenative polymerization. The average molecular weight of dehydrogenated polymers (DHPs) was monitored by GPC and correlated to reaction conditions such as time, concentration of substrate, concentration of catalyst, type of oxidation agent,
【 授权许可】
CC BY
© 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland.
【 预 览 】
Files | Size | Format | View |
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RO202003190054839ZK.pdf | 1215KB | download |