Polymers | |
Random Poly(Amino Acid)s Synthesized by Ring Opening Polymerization as Additives in the Biomimetic Mineralization of CaCO3 | |
Vladimir Dmitrovic1  Gijs J.M. Habraken2  Marco M.R.M. Hendrix1  Wouter J.E.M. Habraken1  Andreas Heise2  Gijsbertus de With1  | |
[1] Laboratory of Materials and Interface Chemistry and Soft Matter CryoTEM Unit, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, Eindhoven 5600 MB, The Netherlands;Laboratory of Polymer Chemistry, Eindhoven University of Technology, P.O. Box 513, Eindhoven 5600 MB, The Netherland; | |
关键词: biomineralization; polypeptide; NCA; vaterite; hybrid materials; | |
DOI : 10.3390/polym4021195 | |
来源: mdpi | |
【 摘 要 】
Biominerals such as bones, teeth and seashells, very often have advanced material properties and are a source of inspiration for material chemists. As in biological systems acidic proteins play an important role in regulating the formation of CaCO3 biominerals, we employ poly(amino acid)s to mimic the processes involved in the laboratory. Here we report on the synthesis of random aminoacid copolymers of glutamic acid (Glu), lysine (Lys) and alanine (Ala) using the ring opening polymerization (ROP) of their respective
【 授权许可】
CC BY
© 2012 by the authors; licensee MDPI, Basel, Switzerland.
【 预 览 】
Files | Size | Format | View |
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RO202003190043980ZK.pdf | 450KB | download |