Functional Conducting Polymers via Thiol-ene Chemistry

Biosensors

Kathleen E. Feldman¹ 

[1] Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA; E-Mail

关键词: conducting polymer;    thiol-ene;    ProDOT;    functionalization;   

DOI  :  10.3390/bios2030305

来源: mdpi

【 摘 要 】

We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.

【 授权许可】

CC BY   
© 2012 by the authors; licensee MDPI, Basel, Switzerland.