Materials | |
A Review on Breathing Behaviors of Metal-Organic-Frameworks (MOFs) for Gas Adsorption | |
Mays Alhamami1  Huu Doan1  | |
[1] Department of Chemical Engineering, Ryerson University, 350 Victoria Street, Toronto, ON M5B 2K3, |
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关键词: metal-organic frameworks (MOFs); breathing; gas adsorption; gas storage; flexibility; post-synthetic modifications (PSM); | |
DOI : 10.3390/ma7043198 | |
来源: mdpi | |
【 摘 要 】
Metal-organic frameworks (MOFs) are a new class of microporous materials that possess framework flexibility, large surface areas, “tailor-made” framework functionalities, and tunable pore sizes. These features empower MOFs superior performances and broader application spectra than those of zeolites and phosphine-based molecular sieves. In parallel with designing new structures and new chemistry of MOFs, the observation of unique breathing behaviors upon adsorption of gases or solvents stimulates their potential applications as host materials in gas storage for renewable energy. This has attracted intense research energy to understand the causes at the atomic level, using
【 授权许可】
CC BY
© 2014 by the authors; licensee MDPI, Basel, Switzerland
【 预 览 】
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RO202003190026623ZK.pdf | 3236KB | download |