Metal-Organic Frameworks for Highly Selective Separations

Omar M. Yaghi

关键词: ADSORPTION;    GASES;    METHANE;    ORGANIC COMPOUNDS;    STORAGE;    SURFACE AREA metal-organic framework;    gas adsorption;    gas separation;   

DOI  :  10.2172/964683
RP-ID  :  DOE/ER/15813
PID  :  OSTI ID: 964683
Others  :  TRN: US201202%%804

美国|英语

来源: SciTech Connect

【 摘 要 】

This grant was focused on the study of metal-organic frameworks with these specific objectives. (1) To examine the use of MOFs with well-defined open metal sites for binding of gases and small organics. (2) To develop a strategy for producing MOFs that combine large pore size with high surface area for their use in gas adsorption and separation of polycyclic organic compounds. (3) To functionalize MOFs for the storage of inert gases such as methane. A brief outline of our progress towards these objectives is presented here as it forms part of the basis for the ideas to be developed under the present proposal.