RutheniumII Complexes bearing Fused Polycyclic Ligands: From Fundamental Aspects to Potential Applications

Molecules

Ludovic Troian-Gautier¹ 

[1] Laboratoire de Chimie Organique et Photochimie, Université Libre de Bruxelles (ULB), CP160/08, 50 av. F. D. Roosevelt, 1050 Bruxelles, Belgium; E-Mail

关键词: ruthenium^II;    polypyridyl;    polyazaaromatic;    extended π-system;    photo-catalysis;    photophysics;   

DOI  :  10.3390/molecules19045028

来源: mdpi

【 摘 要 】

In this review, we first discuss the photophysics reported in the literature for mononuclear ruthenium complexes bearing ligands with extended aromaticity such as dipyrido[3,2-a:2',3'-c]phenazine (DPPZ), tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]-phenazine (TPPHZ), tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]acridine (TPAC), 1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene (PHEHAT) 9,11,20,22-tetraaza- tetrapyrido[3,2-a:2',3'-c:3'',2''-l:2''',3'''-n]pentacene (TATPP), etc. Photophysical properties of binuclear and polynuclear complexes based on these extended ligands are then reported. We finally develop the use of binuclear complexes with extended π-systems for applications such as photocatalysis.

【 授权许可】

CC BY   
© 2014 by the authors; licensee MDPI, Basel, Switzerland.