Synthesis and Molecular Structure of 2-(Diphenylphosphano)phenyl Benzoate Borane Adduct

Crystals

Constantin Mamat²  Martin Kཬkerling¹ 

[1] Institut für Chemie, Universität Rostock, Anorganische Festkörperchemie, Albert-Einstein-Straße 3a, D-18059 Rostock, Germany;Institut für Radiopharmazie, Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstraße 400, D-01328 Dresden, Germany; E-Mail:

关键词: building block;    Lewis acid-base;    Staudinger Ligation;   

DOI  :  10.3390/cryst5010009

来源: mdpi

【 摘 要 】

The crystal and molecular structure of 2-(diphenylphosphano)phenyl benzoate borane adduct are reported. The title compound crystallizes from a petroleum ether/ethyl acetate mixture in the triclinic space group Pwith two molecules in the unit cell. The unit cell parameters are: a = 8.67(1) Å, b = 9.202(1) Å, c = 14.224(2) Å; α = 72.600(7)°, β = 73.577(7)°, γ = 84.349(7)° and V = 1039.5(2) ų. Bond lengths and angles are typical for this phosphane borane adduct.

【 授权许可】

CC BY   
© 2014 by the authors; licensee MDPI, Basel, Switzerland.