Post-Synthetic Shaping of Porosity and Crystal Structure of Ln-Bipy-MOFs by Thermal Treatment

Molecules

Philipp R. Matthes²  Fabian Schönfeld²  Sven H. Zottnick²  Klaus Müller-Buschbaum¹ 

[1] Institute of Inorganic Chemistry, University of Würzburg, Am Hubland, 97074 Würzburg, Germany;

关键词: metal-organic frameworks;    shaping of porosity;    thermal treatment;    Ln-MOFs;    luminescence;    crystal structure;   

DOI  :  10.3390/molecules200712125

来源: mdpi

【 摘 要 】

The reaction of anhydrous lanthanide chlorides together with 4,4′-bipyridine yields the MOFs[Gd₂Cl₆(qtpy)₂(bipy)₂]·bipy. Altogether, the manuscript elaborates the influence of thermal treatment beyond the usual activation procedures reported for MOFs.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.