Coordination Polymers and Metal Organic Frameworks Derived from 1,2,4-Triazole Amino Acid Linkers

Polymers

Anil D. Naik¹  Marinela M. Dîrtu¹  Antoine P. Railliet¹  Jacqueline Marchand-Brynaert¹ 

[1] Institute of Condensed Matter and Nanosciences, Université Catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium;

关键词: coordination polymer;    metal-organic frameworks;    amino acids;    transamination;   

DOI  :  10.3390/polym3041750

来源: mdpi

【 摘 要 】

The perceptible appearance of biomolecules as prospective building blocks in the architecture of coordination polymers (CPs) and metal-organic frameworks (MOFs) are redolent of their inclusion in the synthon/tecton library of reticular chemistry. In this frame, for the first time a synthetic strategy has been established for amine derivatization in amino acids into 1,2,4-triazoles. A set of novel 1,2,4-triazole derivatized amino acids were introduced as superlative precursors in the design of 1D coordination polymers, 2D chiral helicates and 3D metal-organic frameworks. Applications associated with these compounds are diverse and include gas adsorption-porosity partitioning, soft sacrificial matrix for morphology and phase selective cadmium oxide synthesis, Fe^II spin crossover materials, zinc-β-lactamases inhibitors, logistics for generation of chiral/non-centrosymmetric networks; and thus led to a foundation of a new family of functional CPs and MOFs that are reviewed in this invited contribution.

【 授权许可】

CC BY   
© 2011 by the authors; licensee MDPI, Basel, Switzerland.