Structures and Energetic Properties of Two New Salts Comprising the 5,5'-Azotetrazolate Dianion

Crystals

Raik Deblitz²  Cristian G. Hrib²  Frank T. Edelmann¹ 

[1] Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Magdeburg 39106, Germany;

关键词: energetic salts;    azotetrazolate;    phosphonium;    1H-1;    2;    4-triazole-1-carboxamidine;    hydrogen bonds;   

DOI  :  10.3390/cryst5030405

来源: mdpi

【 摘 要 】

Two new potentially energetic salts comprising the 5,5'-azotetrazolate dianion have been prepared and structurally characterized. The new azotetrazolates are tetraphenylphosphonium-5,5'-azotetrazolate (1) and 1H-1,2,4-triazole-1-carboxamidine-5,5'-azotetrazolate (2). The crystal structures of both compounds have been determined by single-crystal X-ray diffraction and their energetic properties have been tested. Due to its high nitrogen-content of 73.14%, compound 2 was found to be significantly impact-sensitive.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.