Zr-SBA-15 Lewis Acid Catalyst: Activity in Meerwein Ponndorf Verley Reduction

Catalysts

Jose Iglesias¹  Juan Antonio Melero²  Gabriel Morales²  Jovita Moreno²  Yolanda Segura²  Marta Paniagua²  Alberto Cambra²  Blanca Hernández² 

[1] ESCET, Rey Juan Carlos University, C/Tulipán, s/n. Móstoles, E28933 Madrid, Spain;

关键词: mesoporous materials;    heterogeneous catalysis;    Lewis acids;    hydrogen transfer;    zirconium;   

DOI  :  10.3390/catal5041911

来源: mdpi

【 摘 要 】

Zr-SBA-15 Lewis acid catalyst has demonstrated an outstanding catalytic activity in the reduction of several carbonyl compounds by means of Meerwein Ponndorf Verley (MPV) reaction, using several secondary alcohols, and showing a very high selectivity towards the desired products. Special focus was addressed in the catalytic activity of Zr-SBA-15 material in the production of furfuryl alcohol from furfural, which is an important reaction for the lignocellulosic biomass valorization. In this transformation, both the reaction temperature and the i-PrOH:Furfural molar ratio exert a positive influence on the rate of the MPV transformation, with the influence of the former being much higher. i-propyl-furfuryl ether, a by-product resulting from the etherification of the target product with the sacrificing alcohol, is also found together with the main product. The production of this side-product is highly influenced by the reaction temperature, so that low temperatures and high sacrificing alcohol to substrate molar ratios have to be applied to keep its production at low levels.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.