Modified Derivatives of Metal Alkoxides' Hydrolysates: Dispersibility into Organic Media and Photochemical Properties

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

KAZUKI WATANABE¹  SHIMIO SATO¹  TADAHIRO MURAKATA(AITA)¹  YUICHI YOSHIDA¹ 

[1] Department of Materials Science and Engineering, Yamagata University

关键词: Metal Alkoxide;    Hydrolysate;    Modification;    Dispersibility;    Photochemical Property;   

DOI  :  10.1252/jcej.34.1236

来源: Maruzen Company Ltd

【 摘 要 】

References(12)Cited-By(1)Metal alkoxides are hydrolyzed and the hydrolysates are modified with a coupling agent containing alkyl chains. The modified uni-hydrolysates, prepared using each of the alkoxides of Ti, Fe, Al, and Zr, and the modified bi-hydrolysates, prepared using two alkoxides consisting of a given alkoxide as one and Ti or Al alkoxide as the other, are dispersible homogeneously into organic solvents. Organic solutions of the modified bi-hydrolysates show spectral changes with light irradiation when they are prepared using Ti alkoxide. The spectral changes are due to intra- and/or inter-particulate electron transfer from photogenerated Ti3+ to other metal atoms in the hydrolysates. The electron transfer is efficient, which can be explained in terms of extremely fine particle size of the modified hydrolysates.

【 授权许可】

Unknown