Hydroformylation of methyl oleate catalyzed by rhodium complexes

Química Nova

Universidade Federal do Espírito Santo, São Mateus, Brasil¹  Mendes, Ana Nery Furlan¹  Gregório, José Ribeiro¹  Universidade Federal do Rio Grande do Sul, Porto Alegre, Brasil¹  Rosa, Ricardo Gomes da¹ 

关键词: methyl oleate;    hydroformylation;    rhodium.;   

DOI  :  10.1590/S0100-40422012001000010

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

In this work, we describe the hydroformylation of methyl oleate catalyzed by several rhodium complexes. Parameters including total pressure, phosphorous/rhodium and CO/H2 ratio, temperature and phosphorous ligands were scanned. Total conversion of the starting double bonds was achieved while maintaining excellent selectivity in aldehydes.

【 授权许可】

Unknown