Hydroformylation of methyl oleate catalyzed by rhodium complexes

Quimica nova

Mendes, Ana Nery Furlan¹  Gregório, José Ribeiro²  Rosa, Ricardo Gomes da² 

[1] Universidade Federal do Espírito Santo, São Mateus, Brasil;Universidade Federal do Rio Grande do Sul, Porto Alegre, Brasil

关键词: methyl oleate;    hydroformylation;    rhodium.;   

DOI  :  10.1590/S0100-40422012001000010

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

In this work,we describe the hydroformylation of methyl oleate catalyzed by several rhodiumcomplexes. Parameters including total pressure, phosphorous/rhodium and CO/H2ratio, temperature and phosphorous ligands were scanned. Total conversion ofthe starting double bonds was achieved while maintaining excellent selectivityin aldehydes.

【 授权许可】

CC BY