期刊论文详细信息
Journal of the Brazilian Chemical Society | |
Microwave-assisted clean synthesis of amides via aza-wittig reaction under solvent-free condition | |
Nagarajan, Sangaraiah1  Sathishkumar, Murugan1  Dinesh, Murugan1  Madurai Kamaraj University, Tamilnadu, India1  Velan, Poovan Shanmuga1  Ponnuswamy, Alagusundaram1  | |
关键词: microwave; solution phase; solvent-free; amide; aza-wittig; | |
DOI : 10.1590/S0103-50532011001100007 | |
学科分类:化学(综合) | |
来源: SciELO | |
【 摘 要 】
A solvent-free microwave-assisted coupling of phosphazenes with acyl chlorides or carboxylic anhydrides in presence of triethylphosphite has been accomplished resulting in a clean synthesis of amides in good yields. Unlike the prevailing time-consuming solution phase methodologies employing chlorinated solvents, benzene (carcinogenic), etc, the present protocol is an eco friendly, rapid and simple approach.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912050581183ZK.pdf | 1412KB | download |