Domino Knoevenagel/Michael synthesis of 2,2'-arylmethylenebis(3- hydroxy-5,5-dimethyl-2-cyclohexen-1-one) derivatives catalyzed by silica-diphenic acid and their single crystal X-ray analysis

Journal of Chemical Sciences

MONIKA GUPTA1¹  RUPALI VAID¹  RAJNI KANT²  VIVEK K GUPTA² 

[1] Department of Chemistry, University of Jammu, Jammu 180 006, India$$;Post-Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi 180 006, India$$

关键词: Crystal structure;    single crystal X-ray analysis;    5;    5-dimethyl-1;    3-cyclohexanedione;    heterogeneous catalyst.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

An efficient and eco-friendly procedure has been developed for the synthesis of various 2,2'- arylmethylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) derivatives which were isolated and characterizedby melting point, IR,$^{ 1}H-NMR$,$^{ 13}$C-NMR and mass spectrometric techniques. Out of the fourteencompounds synthesized, four compounds yielded crystals suitable for single crystal X-ray analysis whichshowed that 2,2'-phenylmethylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) crystallizes in the tetragonalsystem with space group I41/a, 2,2’-(3-nitrophenyl)methylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) crystallizes in the monoclinic system with space group P21/n, 2,2’-(4-nitrophenyl)methylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) crystallizes in the orthorhombic system with space group Pca21and 2,2’-(4-chlorophenyl)methylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexene-1-one) crystallizes in the monoclinicspace group P21/c.

【 授权许可】

Unknown