Study towards diversity oriented synthesis of optically active substituted cyclopentane fused carbocyclic and oxacyclic medium-sized rings: Competition between Grubbs-II catalyzed ring closing olefin metathesis and ring closing carbonyl-olefin metathesis

Journal of Chemical Sciences

S C ROY¹  P CHAKRABORTY¹ 

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关键词: Diversity-oriented synthesis;    bicyclic frameworks;    ring closing metathesis;    Grubbs-II catalyst;    carbonyl-olefin metathesis.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

A study towards diversity-oriented synthesis of optically active cyclopentane fused bicyclic frameworks has been accomplished. The common intermediate was prepared from commercially available starting material (S)-carvone. The observations on competition between Grubbs-II catalyzed ring closing metathesis (RCM) and ring closing carbonyl-olefin metathesis (RCCOM) were the key features of the study.

【 授权许可】

Unknown