C(sp2)–C(sp2) cross coupling reaction catalyzed by a palladacycle phosphine complex: A simple and sustainable protocol in aqueous media

Journal of Chemical Sciences

Seyyed Javad Sabounchei1¹  Marjan Hosseinzadeh¹ 

[1] Faculty of Chemistry, University of Bu–Ali Sina, Hamedan, 65174 Iran$$

关键词: Palladium complex;    Heck cross-coupling reaction;    low catalyst loading;    aerobic conditions.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

The Heck reactions of various aryl halides with olefins using {[Ph2PCH2PPh2CH=C(O)(C10H7)] PdCl2} as efficient catalyst has been investigated. The mononuclear palladacycle complex showed excellent activity in aqueous phase including the C(sp2)–C(sp2) cross coupling reactions. The advantages of the protocol are high yields, short reaction time, a cleaner reaction profile and notable simplicity.

【 授权许可】

Unknown