期刊论文详细信息
Journal of The Chilean Chemical Society | |
PALLADIUM COMPLEX BEARING 3,5-BIS(BENZOTRIAZOL-1-YLMETHYL)TOLUENE LIGAND CATALYZES OXIDATIVE AMINATION OF ALLYL BUTYL ETHER | |
PÉREZ, EDWIN G1  ROJAS, RENÉ S2  HURTADO, JOHN2  VALDERRAMA, MAURICIO2  | |
[1] Pontificia Universidad Católica de Chile, Chile;Pontificia Universidad Católica de Chile, Santiago, Chile | |
关键词: Palladium complex; Bidentate nitrogen ligand; Aminopalladation; Oxidative amination; | |
DOI : 10.4067/S0717-97072013000100007 | |
学科分类:化学(综合) | |
来源: Sociedad Chilena de Quimica | |
【 摘 要 】
The reaction of 3,5-bis(bromomethyl)toluene with benzotriazole yields the bidentate ligand 3,5-bis(benzotriazol-1-ylmethyl)toluene (1). This ligand reacts with [PdCl2(cod)] (cod = 1,5-cyclooctadiene) to give the complex [PdCl2{3,5-bis(benzotriazol-1-ylmethyl)tolyl}] (2). These compounds were characterized by elemental analyses, mass spectra, and FTIR and NMR (1H, 13C) spectroscopies. The palladium(II) complex 2 shows high activity as catalyst for oxidative amination, involving allyl butyl ether and phthalimide as substrates and PhICl2 as a stoichiometric oxidant.
【 授权许可】
Unknown
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