Synthesis and structure of bis(𝛽-dibenzoyl methanato -O,O′) (aquo-O) dioxouranium (VI) compound

Journal of Chemical Sciences

S Kannan1²  M G B Drew¹ 

[1] Department of Chemistry, University of Reading, Reading, UK$$;Fuel Chemistry Division, Bhabha Atomic Research Centre, Mumbai, 400 085 India$$

关键词: 𝛽-diketonates;    uranyl ion;    adduct compound;    crystal structure;    hydrogen bonding.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

The compound [UO2(C6H5COCHCOC6H5)2.H2O] was synthesized and characterized by IR, 1H NMR and CHN analysis. Structure of the compound shows that the uranium atom is surrounded by seven oxygen atoms in a pentagonal bi-pyramidal geometry. The water molecule is hydrogen bonded to another molecule via the uranyl and 𝛽-diketonate oxygen atoms to give a linear zig-zag arrangement along the `a' axis. The whole molecule is stabilized in solid state by various intermolecular hydrogen bonding interactions.

【 授权许可】

Unknown