Three Novel Lanthanide Metal-Organic Frameworks (Ln-MOFs) Constructed by Unsymmetrical Aromatic Dicarboxylatic Tectonics: Synthesis, Crystal Structures and Luminescent Properties

Molecules

Ya-Pan Wu²  Dong-Sheng Li¹  Wei Xia²  Sha-Sha Guo² 

[1] College of Materils & Chemical Engineering, Collaborative Innovation Center for Microgrid of New Energy of Hubei Province, China Three Gorges University, Yichang 443002, China

关键词: Ln (III) coordination polymers;    crystal structure;    topology;    luminescent properties;   

DOI  :  10.3390/molecules190914352

来源: mdpi

【 摘 要 】

Three novel Ln(III)-based coordination polymers, {[Ln₂ (2,4-bpda)₃ (H₂O)_x]·yH₂O}_n (Ln = La (III) (1), x = 2, y = 0, Ce (III) (2), Pr (III) (3), x = 4, y = 1) (2,4-H₂bpda = benzophenone-2,4-dicarboxylic acid) have been prepared via a solvothermal method and characterized by elemental analysis, IR, and single-crystal X-ray diffraction techniques. Complex 1 exhibits a 3D complicated framework with a new 2-nodal (3,7)-connected (4²·5) (4⁴·5¹·6⁶·8) topology. Complexes 2 and 3 are isomorphous, and feature a 3D 4-connected (6⁵·8)-CdSO₄ network. Moreover, solid-state properties such as thermal stabilities and luminescent properties of 1 and 2 were also investigated. Complex 1 crystallized in a monoclinic space group P2₁/c with a = 14.800 (3), b = 14.500 (3), c = 18.800 (4) Å, β = 91.00 (3), V = 4033.9 (14) ų and Z = 4. Complex 2 crystallized in a monoclinic space group Cc with a = 13.5432 (4), b = 12.9981 (4), c = 25.7567 (11) Å, β = 104.028 (4), V = 1374.16 (7) ų and Z = 4.

【 授权许可】

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