Application of bisphosphomide-palladium(II) pincer complex in Suzuki-Miyaura cross-coupling reaction under microwave irradiation

Journal of Chemical Sciences

Maruthai Kumaravel¹  Maravanji S Balakrishna1¹  Pawan Kumar¹ 

[1] Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India$$

关键词: Pincer complex;    bisphosphomide;    Suzuki-Miyaura coupling;    microwave irradiation;    palladium(II).;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

The bisphosphomide-based pincer complex [PdBr{2,6-{Ph2PC(O)}2(C6H3)}] (2) has shown very high catalytic activity in Suzuki-Miyaura cross coupling reaction under microwave irradiation for a variety of aryl bromides and aryl boronic acids. The complex showed the same efficiency for gram scale reactions.

【 授权许可】

Unknown