Inorganic-organic hybrid framework solids

Journal of Chemical Sciences

Srinivasan Natarajan1¹ 

[1] Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur PO, Bangalore 560 064, India$$

关键词: Framework;    iron phosphate-oxalate structures;    hybrid structures;    crosslinked oxalates;    self-organization;    structure-directing amine.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

Recent developments in the area of hybrid structures are overviewed with special emphasis on iron phosphate-oxalate materials. The structure of the iron phosphate-oxalates consists of iron phosphate chains or layers that are connected by oxalate moieties completing the architecture. The compounds exhibit interesting magnetic properties originating from the super-exchange interactions that are predominantly anti-ferromagnetic, involving the iron phosphates and the oxalate moieties. One of the materials, IV, also exhibits interesting adsorptive properties reminiscent of aluminosilicate zeolites. The aluminum phosphate-oxalate, VII, indicates that hybrid structures can be formed with zeolite architecture.

【 授权许可】

Unknown