Dynamics of different molecules adsorbed in porous media

Pramana

N M Gupta²  R Mukhopadhyay¹  V S Kamble²  S Mitra¹  A K Tripathi² 

[1] Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai 400 085, India$$;Applied Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085, India$$

关键词: Porous materials;    diffusion;    neutron scattering.;   

DOI  :  

学科分类：物理（综合）

来源: Indian Academy of Sciences

【 摘 要 】

We present in this paper a comparative study on the dynamics of benzene, cyclohexane, and methanol molecules, confined in the pores of MCM-41 molecular sieve and HZSM-5 zeolite. The quasi-elastic neutron scattering (QENS) measurements revealed that the physical state of these adsorbed molecules depended not only on the structural characteristics of the host matrix but also on the chemical properties, such as dipole moment, of the guest molecules. Thus, while no motion was observed in the time-scale of 10−10 –10−12 s in the case of methanol, the larger size benzene and cyclohexane molecules are found to perform six-fold and three-fold jump rotation, respectively, when adsorbed inside the cages of HZSM-5 at room temperature. At the same time, all the three molecules are found to undergo a translational motion inside the pores of MCM-41 molecular sieves, the value of diffusion constant being the lowest in case of methanol because of its higher polarity. Translationl motion of the guest molecules inside the pores of MCM-41 can be satisfactorily described by Chudley–Eliott fixed jump length diffusion and accordingly the residence time, jump length and diffusion constant are estimated.

【 授权许可】

Unknown