An Efficient Synthesis of Phospha-Morita-Baylis-Hillman Adducts via Michaelis-Arbuzov Reaction of the DABCO Salt of Morita-Baylis-Hillman Bromide

Bulletin of the Korean chemical society

Hyun Seung Lee¹  Se Hee Kim¹  Jae Nyoung Kim¹  Sung Hwan Kim¹ 

关键词: Phospha-Morita-Baylis-Hillman adducts;    Michaelis-Arbuzov reaction;    DABCO salt;    Allylic phosphonates;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

An efficient synthesis of phospha-Morita-Baylis-Hillman adducts was carried out in good yields via the Michaelis-Arbuzov reaction of the DABCO salts of MBH bromides. Instead of a DABCO salt, a phosphonium salt could be effectively used for some substrates which showed some problems in the presence of DABCO.

【 授权许可】

Unknown