Theoretical Studies on Nitramine Explosives with -NH2 and -F Groups

Bulletin of the Korean chemical society

Guo Zheng Zhao¹  Ming Lu¹ 

关键词: RDX;    HMX;    Density functional theory (DFT);    Thermodynamic properties;    Detonation performances;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The nitramine explosives with -NH2 and -F groups were optimized to obtain their molecular geometries and electronic structures at DFT–B3LYP/6-31+G(d) level. The theoretical molecular density (ρ), heat of formation (HOF), detonation velocity (D) and detonation pressure (P), estimated using Kamlet-Jacobs equations, showed that the detonation properties of these compounds were excellent. Based on the frequencies scaled by 0.96 and the principle of statistic thermodynamics, the thermodynamic properties were evaluated, which were respectively related with the temperature. The simulation results reveal that 1,3,5,7-tetranitro-1,3,5,7-tetrazocan-2- amine (molecule B1) performs similarly to the famous explosive HMX, and 2-fluoro-1,3,5-trinitro-1,3,5- triazinane (molecule C1) and 2-fluoro-1,3,5,7-tetranitro-1,3,5,7-tetrazocane (molecule D1) outperform HMX. According to the quantitative standard of energetics and stability as an HEDC (high energy density compound), molecules C1 and D1 essentially satisfy this requirement. These results provide basic information for molecular design of novel high energetic density compounds.

【 授权许可】

Unknown