The Modified Electrode by PEDOP with MWCNTs-Palladium Nanoparticles for the Determination of hydroquinone and Catechol

Bulletin of the Korean chemical society

Orogzodmaa Naranchimeg¹  Seungwon Jeon¹  Seul Ki Kim¹ 

关键词: Hydroquinone;    Catechol;    Electrochemical sensor;    Carbon nanotubes;    MWCNTs-palladium nanoparticles;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Poly-ethylenedioxypyrrole (PEDOP) coated thiolated multiwall carbon nanotubes palladium nanoparticles (MWCNTs-Pd) modified glassy carbon electrode (GCE) [PEDOP/MWCNTs-Pd/GCE] for the determination of hydroquinone (HQ) and it’s isomer catechol (CA) were synthesized and compared with bare GCE and thiolated multiwall carbon nanotubes (MWCNTs-SH/GCE). The modification could be made by simple processes on a GCE with MWCNTs-Pd covered by PEDOP in a 0.05 M tetrabutylammonium perchlorate (TBAP)/MeCN solution system. A well-defined peak potential evaluation of the oxidation of hydroquinone to quinone at 0.05 V (vs. Ag/AgCl), and electrochemical reduction back to hydroquinone were found by cyclic voltammetry (CV) in phosphate buffered saline (PBS) at pH 7.4. Peak current values increased linearly with increasing hydroquinone contents. The peak separation between the anodic and cathodic peaks at the PEDOP/ MWCNTs-Pd/GCE was ΔEp = 40 mV for HQ and ΔEp = 70 mV for CA, resulting in a higher electron transfer rate. Moreover, good reproducibility, excellent storage stability, a wide linear range (0.1 μM - 5 mM for HQ and 0.01 μM - 6 mM for CA), and low detection limits (2.9 × 10−8 M for HQ and 2.6 × 10−8 M for CA; S/N = 3) were determined using differential pulse voltammetry (DPV) and amperometric responses; this makes it a promising candidate as a sensor for determination of HQ and CA.

【 授权许可】

Unknown