Efficient, Rapid and Solvent-free Cyanosilylation of Aldehydes and Ketones Catalyzed by SbCl3

Bulletin of the Korean chemical society

S. A. Pourmousavi H. Salahshornia¹ 

关键词: SbCl3;    Trimethylsilyl cyanide;    Trimethylsilylethers;    Solvent free conditions;    TMSCN;    Carbonyl compounds;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Antimony trichloride (SbCl3) was demonstrated to be an effective catalyst for the cyanosilylation of a wide variety of carbonyl compounds under solvent-free conditions. The reactions proceeded smoothly at room temperature to afford the corresponding cyanosilylethers in good to excellent yields.

【 授权许可】

Unknown