Microwave Synthesis of a Porous Metal-Organic Framework,Nickel(II) Dihydroxyterephthalate and its Catalytic Propertiesin Oxidation of Cyclohexene

Bulletin of the Korean chemical society

Young Kyu Hwang¹  Shiva B Halligudi¹  Nak Han Jang¹  Ji Sun Lee¹  Jong San Chang¹  Dong Won Hwang¹ 

关键词: MOF materials;    Ni-CPO-27;    Microwave synthesis;    Epoxidation;    Cyclohexene;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

A porous coordination solid of nickel(II) dihydroxyterephthalate has been synthesized by the microwave-assisted (MW) method. The synthesized nickel(II) dihyroxylterephthalate was designated by the general formula of [Ni₂(dhtp) (H₂O)₂]·8H₂O (where, dhtp = 2,5-dihydroxyterephthalate, denoted by Ni-DHTP). The effect of microwave-irradiation temperature and time of irradiation on the porosity and morphological changes in the solids have also been investigated. The catalytic performance of Ni-DHTP synthesized by MW method has been studied in the oxidation of cyclohexene with aqueous H₂O₂, which gave cyclohexene oxide as the primary product and 2-cyclohexene-1-ol as a major product.

【 授权许可】

Unknown