Efficient Biomimetic Oxidative Decarboxylation of Some Carboxylic Acids Catalyzed by a Manganese (III) Schiff Base Complex

Bulletin of the Korean chemical society

Parisa Akhlaghi¹  Masoud Nasr Esfahani¹  Morteza Montazerozohori¹ 

关键词: Schiff base;    Complex;    Catalytic;    Decarboxylation;    Manganese(III);   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The four dentate N2O2 Schiff base ligand of bis(2-hydroxyacetophenone)-1,2-propanediimine (BHAPN) and its manganese (III) complex were synthesized and identified by microanalysis, spectral data (1H NMR, MS, FT-IR and UV-Visible) and molar conductivity measurement. The mild and efficient homogeneous oxidative decarboxylation of some carboxylic acids by catalytic amount of this manganese (III) complex, using tetrabutylamonium periodate as a mild oxidant in chloroform at room temperature is reported. The catalyst used in this study showed good activity for the decarboxylation of the titled compounds.

【 授权许可】

Unknown