期刊论文详细信息
Bulletin of the Korean chemical society | |
A Convenient Synthesis of Polycyclic ¥ã-Lactams via Pauson-Khand Reaction | |
Joo Hee Lee1  Sung Hoon Kim1  Yong Hoon Kim1  Hea Jeong Kim1  Seok Won Kang1  | |
关键词: Polycyclic ¥ã-lactams; Pauson-Khand reaction; 5; 6; 5 Fused ring systems; Co2(CO)8; | |
DOI : | |
学科分类:化学(综合) | |
来源: Korean Chemical Society | |
【 摘 要 】
Pauson-Khand reaction of hydroxyenynes with Co2(CO)8 in the presence of N-methylmorpholine N-oxide or trimethylamine N-oxide as a promoter produced polycyclic �?-lactams as single stereoisomers in moderate to excellent yield. These are the first examples of an intramolecular Pauson-Khand reaction on a hydroxyenyne system tethered to a three- and four-membered ring as new skeletons with 5,6,5 fused ring systems.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912010241486ZK.pdf | 315KB | download |