Twist Boat Conformation of Thiane S-Oxide Both in Solid State and in Solution

Bulletin of the Korean chemical society

Dong Ju Jeon¹  Ikyon Kim¹ 

关键词: Twist boat;    Conformational analysis;    X-ray crystallography;    Thiane S-oxide;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

A stable twist boat conformation of thiane S-oxide 1a in solid state and in solution was unambiguously determined by single crystal X-ray crystallography and solution NMR analyses. On the contrary, the thiane Sdioxide 2 which was obtained from the oxidation of corresponding thiane S-oxide 1a was confirmed to adopt a regular chair conformation.

【 授权许可】

Unknown